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Ozone on the Rise in the Mid-Troposphere

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Ozone is on the rise in the mid-troposphere (10-16,000 ft.), and the source traces back to China and India. This contrasts with the air quality index, of which ozone is a principal component, which has improved around most major metropolitan areas.

Ozone is a complex subject. High in the stratosphere it is good because it absorbs ultraviolet radiation. A decline in stratospheric ozone became a concern several years ago (the ozone hole). But at ground level ozone is harmful. It is a powerful oxidizer that is harmful to most living matter.

Ozone in the lower atmosphere is thought to be quickly decomposed. Thus, any that exists is generally thought to be created freshly from a mixture of sunlight and ozone precursor gases (nitrogen oxides and others). Thus, the ozone level is higher during the summer and during the day (more sunshine), lower during the winter and during the night. Cars and power plants emit lots of ozone precursors, which is why ozone is of concern around major metropolitan areas.

Ozone HawaiiBut could industrialized areas create so much ozone precursor that it rises in the atmosphere, traveling to distant places and forming ozone there?

The graphic at right shows the level of ozone measured at Mauna Loa and Hilo, Hawaii. Mauna Loa is 11,145 ft. above sea level, Hilo is at sea level.

(Click on graph for larger view.)

First, notice that there is a yearly peak and a yearly trough, representing the difference between summer and winter. Second, notice that the ozone level on Mauna Loa increased over the time period, but the level at Hilo did not.

This finding parallels the results from another study that used an airplane to repeatedly measure the ozone level over the western United States. Ozone Western USThe second chart at right shows the results. On this complicated chart, the yellow marks represent the median yearly measurement, and the yellow line represents their trend. The green marks show the mean of the yearly measurements, and the red and blue lines show the 67% and 95% confidence intervals.

(Click on graph for larger view.)

Let’s stay with just the median of the yearly measurements (yellow). It has climbed significantly, from below 50 ppb. to over 60 ppb.

These measurements were taken 10-16,000 feet above the earth, similar to the height of Mauna Loa. Interestingly, the study failed to find a similar increase in ozone at lower levels, mirroring the results in Hilo.

The authors concluded that the ozone over Hawaii and the western United States is being formed from a mixture of local sunlight and precursor gases that originate in India and China. Ozone PlumeIn the third graphic at right, the maps on the left shows a plume of increased ozone readings that originates in Asia, and which extends completely across the Pacific Ocean.

(Click on map for larger view.)

Thanks to Dr. Jack Fishman of St. Louis University who got me started on background air pollution. He has a paper in review that compares the ozone level of air entering and exiting the St. Louis region, and the impact of ozone on plants in this area. I hope to report on it once it has been accepted for publication.

Sources:

The graphics above come from a PowerPoint presentation: Cooper, Owen. (2013). Global Surface Ozone Trends, a Synthesis of Recently Published Findings. Given at the NOAA GMD Global Monitoring Annual Conference, May 21-22, Boulder, CO. http://www.researchgate.net/publication/41103085_Increasing_springtime_ozone_mixing_ratios_in_the_free_troposphere_over_western_North_America/file/32bfe50e5aeebd8bce.pdf.

The article detailing the research over the wester United States is: Cooper, O.R., D.D. Parrish, A. Stohl, M. Trainer, P. Nedelec, V. Thouret, J.P. Cammas, S.J. Oltmans, B.J. Johnson, D. Tarasick, T. Leblanc, I.S. McDermid, D. Jaffe, R. Jaffe, R. Gao, J. Stith, T. Ryerson, K. Aikin, T. Campos, A. Weinheimer, & M.A. Avery. (2010). Increasing Springtime Ozone Mixing Ratios in the Free Troposphere Over Western North America. Nature, 463,(21), 334-348. Nature, charges a fee for access to its articles. I was, however, able to download a free copy of the article from Research Gate: http://www.researchgate.net/publication/41103085_Increasing_springtime_ozone_mixing_ratios_in_the_free_troposphere_over_western_North_America/file/32bfe50e5aeebd8bce.pdf.

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